if your main is a druid that you want to make leather gear for, you'll have to do leatherworking. and if you need skins somehow, you'll have to take skinning. there's your 2.
on the other hand, enchanting any leather gear your druid gets for himself is also useful, though only every few levels.
so far i'm at about lvl 150 leatherworking and i'm only at the lvl 20 gear items. around lvl 175 LW, i can make the lvl 30 gear items.
alternatively, you make a 3rd char which is a rogue that can also wear the low level leather gear. your 2nd char is an enchanter that can enchant gear for the rogue to start out. a rogue on a pvp server can be such good fun!
so your rogue can make his own leather gear with skinning and LW, your druid supplies your rogue with potions, and your other char, probably a cloth-wearer, does tailoring and enchanting. i have found that with tailoring and LW even at low levels, you can supply your enchanter with plenty of green gear to get a lot of the starting enchanting ingredients.
level them all up together and you can supply your own enchanter while making endless green gear to level up tailoring and LW.