If you are really intrested in doing enchanting then don't start with a lvl 1 main char. Probably one of the better things to do is get get your main at a decently high lvl (say high 40's to 50's) and then supply your alt Enchanter with most of the stuff that they will need.
For example: My lvl 50+ Rogue can solo the Deadmines, Stockades, BDF, Orc Camps, SM ect... Generally I can come out of the deadmines with 20 or so nonsoulbound green items which I will send to my alt tailor/enchanter along with all the cloth I picked up. I kid you not, by the time I hit lvl 10 I was capped at both tailoring and enchanting until lvl 20 (my alt mage is now lvl 21 and halfway capped on both Tailoring and Chanting).
Another advantage of having a high lvl toon do all the work for you is that you can pick up some pretty kick butt armor/weps for the alt. When you can solo a instance there is no need to share or roll the drops. Anyway that has seemed a pretty effective way to get to 225 in tailoring and chanting.
There is a pretty good guide on getting to 225 btw (I really dont know why this isnt a sticky in this forum but it is in the guides section):
Edited, Tue May 24 10:55:53 2005 by Paraclease