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higher lvl. Herbs can be sold for at least 1gold per count
I would go look at the AH on your server, i know that stuff like Ghost Mushrooms sell well on some servers(as much as 3 gold) but not on mine, if I could get 50 silver I would be impressed.
seonc poster got it right, pick skinning and either mining or herb, trying to track both is a PITA, some herbs will sell for more than skinns, but remember skills are used more often, with the excepiton of wildvine and fadeleafe only alchemest use herbs, skinns are used by LW,BS,Tayloring,engenering, so if you skinn you have a lot more folks to buy you product. High price is only relevent if it sells.