It also lets you watch videos from Youtube channels that are blocked outside the UK, so you can watch Misfits, The Inbetweeners, IT Crowd, and Shameless, which I'm not sure if any of which got broadcasted outside the UK, so ignore me if you've already seen them all. Granted, I'm considerably younger than Nobby, so some people around here might prefer his suggestions.
Also, from iPlayer, watch Have I got News for You, and Nevermind the Buzzcocks. I miss Mark Lamar, but at least Simon Amstell is gone.