That's correct. The same information with a little more detail:
1 Defense Skill
= 0.04% Block
= 0.04% Dodge
= 0.04% Parry
= 0.04% Miss
Or 0.16% combined block + avoidence, or 0.12% pure avoidence.
6 Defense Skill is then a little less than 1% Block + Avoidence and 9 Defense Skill is then a little more than 1% PURE avoidence. 25 Defense Skill adds exactly 1% to all four.
It takes just under 5 Defense Rating (4.92 if you want a little more precision) at level 80 to add 1 Defense Skill.
If you're thinking of going with Dodge rather than defense for avoidence enchants, you might consider it. Thanks to the new avoidence system it is actually in your favor to stack Defense and Dodge incrementally to maximize the effectiveness of your pure avoidence. Of course, this means you already have 540 Defense in the first place -- if not, start there.