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As for raiding... I'm not going to pretend I know the slightest bit about warlock raiding, but I'd say 0/20/41 would turn into 0/20/51... Chaos bolt to me is just screaming "PICK ME IM A RAID TALENT". On the other hand; it would find some use in PvP... Throwing it onto a 5% hp bubbled paladin anyone?
Problem with that is that the destro build is 0/21/40, not 20/41. You have to spend 21 points to get Demo Sac. Will Chaos Bolt be able to provide more damage that Sacing The Succubus? No telling until it is tested with the stats that are available at that level.
For Destro I could see this working:
19/0/52 If Chaos Bolt is worth it, I would probably move away from Demo altogether since Sacrifice is no longer an option. Insta Empowered Corruption. Combined with Molten Core, it appears as though fire damage will be OP. With Chaos Bolt being on an 8 second CD, a sequence with this type of build would probably look like Chaos Bolt > Corr > Immo > Incinerate/Chaos Bolt. Both Immo and Corr would trigger Molten Core, increasing Incinerate damage. Due to Eternal Flames, Immo would not need to be refreshed, so all you'd be concerned with is refreshing core, using Chaos Bolt when available, and Incinerate.
With Demonology, you still have 2 choices. The Succubus now can get healed instead of taking damage with Love Struck. Demo still seems to provide some very solid buffs via Master Demonologist with Succy out, and with Fel Synergy and Demonic Pact. Same could be done with Felgurad, though you'd lose 5% crit from Master Demo and gain 5% damage mitigation.. After deciding on a pet, and skipping metamophisis, since it's not really for damage, take the normal path to ruin.
Affliction looks nice too:
50/0/21 With Eradication that increases cast speed, you can DoT and SB spam faster. Death's Embrace than Increases the Crit Strike chance of SB by 15%!! With Ruin this could be devastating. With Everlasting Affliction, you'd never have to re-apply Corr.
Cast sequence could be: Curse > Corr > SL > UA > SB spam re-applying DoTs as needed
Which will be best will totally depend on how they adjust these talents, and spells, and howwell each spell scales with gear via spell coefficients. None of this info is really known right now, so this is all purely speculation.
Just for ***** and grins I'm gonna bookmark these and see if my predictions come true on these specs.